Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Sekiguchi, Tetsuhiro; Ikeura, Hiromi*; Baba, Yuji
Surface Science, 532-535(1-3), p.1079 - 1084, 2003/06
Using a newly developed rotatable time-of-flight mass spectrometer(R-TOF-MS) and polarized synchrotron radiation, we have investigated orientation effect on fragmentation and desorption pathways occurring at the top-most layers of molecular solids. Reported will be polarization-angle dependencies of TOF mass spectra, high-resolution electron- and ion-NEXAFS in condensed formic acid, formamide and benzene. For condensed formamide(HCOND), marked orientation effect was observed for the enhanced H-yields following C1s * resonance. Direct photodissociation and charge-neutralization play an important role in the effect. For some fragment species, however, the bond scission showed no polarization dependence when dissociation sites were far from core-excited atoms. This is the case for N-D scission and D-desorption following C1s excitation, suggesting that indirect process governs, where secondary electrons would induce the fragmentation.
Yoshigoe, Akitaka; Teraoka, Yuden
Surface Science, 532-535, p.690 - 697, 2003/06
Times Cited Count:22 Percentile:69.36(Chemistry, Physical)no abstracts in English